HOMENews release

Environmentally Friendly Semiconductor Cleaning Device Became a Reality.
SHARP MANUFACTURING SYSTEMS CORPORATION Has Developed
High Temperature/High Concentration Ozone Water Generating Devices.


03 December 2007

SHARP MANUFACTURING SYSTEMS CORPORATION has developed a high temperature/high concentration ozone water generating device designed for semiconductors. It allows you to replace chemical solutions, such as sulfuric acid solutions, used in semiconductor manufacturing processes in large quantities with ozone water, which enables manufacturing semiconductors with no or with extremely small amount of chemical solutions.

A large amount of chemical solution is used when manufacturing semiconductors. However, thanks to the environmentally friendly activities of recent years, the amount of chemical solutions used per unit area for silicon is decreasing by optimizing the concentration of chemical solutions or recycling used chemical solutions. This device is designed to radically reduce the amount of such chemical solutions to be used. The used ozone water will be resolved into oxygen and water and no damage will be caused to the environment.

In order to solve the problem of the poor process capacity of the conventional cleaning methods using the conventional ozone water, we have developed our unique technologies as described below, utilizing our own manufacturing technologies for cleaning devices and the semiconductor technologies within the Sharp group. The following technologies provide practical cleaning processes even in a resist stripping process where the cleaning efficiency becomes poor with the conventional ozone water, by cleaning semiconductor substrates with a supersaturated concentration of high temperature/high concentration ozone water. Moreover, we can expect that the ozone water of high purity generated from pure water and high purity gas can be deployed for miniaturization.


Photo: Overview of the High Temperature/High Concentration Ozone Water Generating Device

Key Points of the Developed Technologies (Patent Pending)
1. The technology to generate a supersaturated concentration of high temperature/high concentration ozone water.
2. The technology to deliver ozone water to the substrate surfaces maintaining a high concentration.
3. The technology to quickly replace the ozone water after reaction on the substrate surfaces and continuously supply fresh ozone water.

<Features of the High Temperature/High Concentration Ozone Water Generating Device>
1. The technology to generate a supersaturated concentration of high temperature/high concentration ozone water.
* When a surplus thermal energy is supplied to ozone water, ozone molecules in a solution will be dissolved into oxygen. We have developed a mechanism that can raise the ozone water temperature to the required temperature in a short time while minimizing the self-decomposition of the ozone molecules in the solution. (Figure 1)

Figure 1: Conceptual Diagram of the High Temperature/High Concentration Ozone Water Generating Device


2. The technology to deliver ozone water to the substrate surfaces maintaining a high concentration.
* Supersaturated ozone water is thermodynamically in a nonequilibrium state and the ozone water concentration will be reduced to the saturating and dissolving concentration over time. We have developed a piping system that extremely reduces the decrease in ozone concentration so that you can use supersaturated high temperature/high concentration ozone water.
3. The technology to quickly replace the ozone water after reaction on the substrate surfaces and continuously supply fresh ozone water.
* We have developed a combined structure that has our proprietary nozzles and substrate rotating mechanism in order to supply high concentration ozone water over substrate surfaces.

<Future Deployment of the Device>
We will incorporate this newly developed device into the semiconductor cleaning device that is now being developed in cooperation with a semiconductor device manufacture. This process with high concentration ozone water will be used as the resist stripping device (patent pending in cooperation with AQUA SCIENCE CO. LTD.) after the high concentration ion implantation process combined with the pre-process using radicals to be generated, and as the cleaning device of the pre-and-post process of the oxide film removing device combined with the dry cleaning device using HF gas plasma. (Figure 2)

Figure 2: Application Example for Environmentally Friendly Devices


We also plan to deploy high temperature/high concentration ozone water for nonsemiconductor purposes, utilizing the effects of ozone, such as its disinfection, deodorization, organic matter decomposition effects and our newly developed technologies.
The resist stripping device after high concentration ion implantation processes that incorporates the high temperature/high concentration ozone water generating device will be exhibited in a joint booth of AQUA SCIENCE CO. LTD. in the SEMICON Japan 2007 to be held from the 5th (Wed) to 7th (Fri) of November. The device will be on the market in 2008.
We expect to sell 10 devices from 2008, and 70 devices by the end of 2010.


<Contact Information on this Matter>
SHARP MANUFACTURING SYSTEMS CORPORATION
Hiroaki Segawa, General Manager of Engineering Dept.4
E-mail: segawa.hiroaki@sharp.co.jp



News Release

Name Release size
High Temperature/High Concentration Ozone Water Generating Devices
03 December 2007 1,139KB

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